No. 1: Amy Winehouse, ‘Rehab’ (2007)

 
During her career, Amy Winehouse was able to stand out with her unique voice and colorful style. She was a true a powerhouse of talent. In 2007, Winehouse broke onto the U.S. scene with a band thanks to her stellar performance of 'Rehab' at the MTV Movie Awards, which sits at No. 1 on our list of the Top 10 MTV Movie Award Performances. Unfortunately, Winehouse passed away in July 2011, but through this video and many other magical moments from her lifetime, we can always remember the songstress for otherworldly vocal talent and captivating stage presence.